363.104 93.067 l f 0 18 612 756 re EMC )Tj !�����:�۪fwOh�KQ3(���g�Z�����l��~�׍�nu�]��M¦���mD ���-�����Ia��6Ss�)����bh�a���g���|:#����kҾ�@X��.1���3Z�{�E��A����=�d�n��x��Y����'�Nx. 1 0 obj<> endobj 2 0 obj<> endobj 3 0 obj<> endobj 5 0 obj<> endobj 7 0 obj<> endobj 8 0 obj<>>> endobj 9 0 obj<> endobj 10 0 obj<><><><><>]/P 9 0 R/S/Article/T()/Pg 11 0 R>> endobj 11 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 12 0 obj<> endobj 13 0 obj[10 0 R] endobj 14 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 15 0 obj[10 0 R] endobj 16 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 17 0 obj[10 0 R] endobj 18 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 19 0 obj[10 0 R] endobj 20 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 21 0 obj[10 0 R] endobj 22 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 23 0 obj[10 0 R] endobj 24 0 obj<> endobj 25 0 obj<> endobj 26 0 obj<> endobj 27 0 obj<> endobj 28 0 obj<> endobj 29 0 obj<>stream 600.467 347.551 l uuid:e963d2fd-ef89-45c1-bd16-f68d10cb2dce f h Overview; Supporting … 362.335 65.388 l 601.236 248.801 l 10.764 383.018 m ( Fisher Scientific )Tj q 362.335 119.207 l T* /TT0 1 Tf (Section 16 - Additional Information )Tj 0 -1.201 TD 122.666 79.612 m 0 -1.201 TD 602.774 701.717 l f f EMC -53.55 -1.556 Td f /Artifact <>BDC h h /TT0 1 Tf ( )Tj /TT0 1 Tf 0 -1.201 TD 5.3819 0 0 5.3819 27.4577 476.7533 Tm f /TT0 1 Tf Wear appropriate protective \ clothing to prevent contact with skin and )Tj Chromium trioxide, anhydrous. ( )Tj (warranty of merchantability or any other warranty, express or implied, w\ ith respect to such information, and we assume no liabil)Tj 604.312 489.539 l 602.774 494.862 l Q 603.543 429.569 l Q 601.236 679.395 l 8.6495 0 0 8.6495 224.6085 110.4134 Tm f 0.313 0.313 0.313 rg EMC (guidelines for the classification determination are listed in 40 CFR Par\ ts 261.3. May impair fertility. (1333-82-0)Tj 43 0 obj <>/Filter/FlateDecode/ID[<863BEA5A25708525D6C2787D460159E2><24CEE00F1470874C9A6A819FD1CC9449>]/Index[22 34]/Info 21 0 R/Length 91/Prev 35069/Root 23 0 R/Size 56/Type/XRef/W[1 2 1]>>stream h h Human TCLo: ROUTE: Inhalatio\ n: DOSE: 110ug/m3. Section 1 - Chemical Product and Company Identification . (For International CHEMTREC assistance, call:)Tj ( R 46 May cause heritable genetic damage. )Tj 120.755 455.71 l 10.7638 0 0 10.7638 7.6884 729.0822 Tm Q Biological limit values List source(s): Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. (is subject to the reporting requirements of Section 313 of SARA Title II\ I and 40 CFR Part 373. 0 18 612 756 re q 121.524 443.024 l 10.7638 0 0 10.7638 7.6884 460.6095 Tm Causes burns by all exposure routes. Q 604.312 518.756 m 0 0 0 rg 11.533 405.314 l %PDF-1.5 %���� (5 \346g/m3 TWA \(listed under )Tj q 10.764 679.395 l q 363.873 66.926 l 455.54 616.781 l /TT0 1 Tf ( Toxic if swallowed, inhaled or absorbed through the skin. 363.873 53.471 l /TT1 1 Tf 0 -1.2 TD 602.774 630.236 l h (Containers may explode in the heat of a fire. /WebCaptureBG BMC (Engineering Controls:)Tj /TT1 1 Tf T* 363.104 93.067 m 362.335 53.471 l f W* n /Artifact <>BDC /TT1 1 Tf Chromium Trioxide is also available in pellets, pieces, powder, sputtering targets, tablets, and nanopowder (from American Elements' nanoscale production facilities). 13.4548 0 0 13.4548 187.5038 141.697 Tm /TT0 1 Tf /TT1 1 Tf (Ingestion:)Tj (MSDS Name:)Tj 306 541.819 m T* 9.226 381.48 593.548 26.141 re $�� ��H�D�X�p"Dp�$�@�8��$ ���V2`�5�.D� �N�d`bd Y���H���7� �f6 This material contains Chromium trioxide (listed as Chromium (VI) compounds), 50%, (CAS# 1333-82-0) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. h Chromium Trioxide Flinn Scientific, Inc. P.O. f h 454.003 630.236 l )Tj 9.226 701.717 593.548 26.141 re 602.774 141.56 l 600.467 161.843 l 362.335 78.843 l ( Use extinguishing media most appropriate for the surrounding fire. 305.231 618.319 l 9.226 253.789 l h 603.543 456.479 l Q 7.688 379.942 l 17.925 1.8 Td ( This material contains Chromium trioxide \(listed as Chromium \(VI\)\ compounds\), >98%, \(CAS# 1333-82-0\) which )Tj h q BT /TT1 1 Tf 7.688 457.248 m 0 -1.201 TD q f 600.467 140.316 l (dusts, vapors, or mists may result in the perforation of the nasal septu\ m. May cause systemic effects. )Tj T* endstream endobj 35 0 obj<> endobj 36 0 obj<> endobj 37 0 obj<>stream 454.771 631.005 m f (Eyes:)Tj Alternate chemical market names/ synonyms . %%EOF 600.467 680.164 l 0.753 0.753 0.753 rg h EMC 0.753 0.753 0.753 rg h (https://fscimage.fishersci.com/msds/95984.htm \(1 of 6\)7/23/2007 11:01:\ 40 AM)Tj 0 18 612 756 re The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. /TT0 1 Tf 0 -1.201 TD /T1_0 1 Tf ( Solid )Tj EMC 10.764 134.584 m 604.312 120.745 l ET 7.688 51.934 l /TT0 1 Tf /Artifact <>BDC /TT0 1 Tf Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Chromium trioxide (CrO3) X X - 215-607-8 - XXXXX Legend: X - Listed 0 18 612 756 re ( 800-424-9300 )Tj 0.801 0.801 0.801 rg 454.771 541.819 l f h h 8.457 541.819 l h (associated with lung cancer and gastrointestinal tract tumors. 604.312 676.32 l 455.54 616.781 l Relevant identified uses of the substance or mixture and uses advised against . /TT0 1 Tf 9.226 471.065 593.548 26.141 re Q (gastrointestinal tract tumors. 602.774 739.538 l 483.757 442.255 l 10.7638 0 0 10.7638 7.6884 236.8076 Tm 10.764 470.259 l /Artifact <>BDC MATERIAL SAFETY DATA SHEET (MSDS) www.lobachemie.com Version: 1 20/05/2016 1/12 CHROMIUM TRIOXIDE 98% MSDS CAS No: 1333-82-0 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. SAFETY DATA SHEET. 7.688 489.539 m W* n 0 -1.201 TD q 600.467 473.371 l 121.524 429.569 l q 0 18 612 756 re /Artifact <>BDC )Tj (Appearance: dark red to purple solid. 13.4548 0 0 13.4548 190.3024 479.7154 Tm )Tj 9.226 443.793 111.529 11.917 re 9.226 141.56 l 7.688 681.703 m Material Safety Data Sheet. 602.774 80.381 l h 10.764 702.46 m 602.774 430.338 l 0 -1.2 TD 0 0 0 rg W* n 602.774 739.538 l 454.003 616.781 l 0 -1 TD h f W* n (Chromium \(VI\) compounds\). T* /TT1 1 Tf h 0 0 0 rg Material Safety Data Sheet. f f 602.774 471.065 l ( )Tj Type of substance Composition: mono-constituent substance Origin: inorganic Total tonnage band Total range: 10 000 - 100 000 tonnes per annum REACH Registered as: FULL Submitted: … /TT0 1 Tf Causes chemical burns to the respiratory tract. T* ET /Artifact <>BDC (from its use. (Material Safety Data Sheet )Tj f 10.764 764.141 m h h 0 -1.201 TD f 10.764 271.866 m Display Name: Chromium trioxide EC Number: 215-607-8 EC Name: Chromium trioxide CAS Number: 1333-82-0 Molecular formula: CrO3 IUPAC Name: trioxochromium . f 0 18 612 756 re ( )Tj EMC -42.948 -1.555 Td 602.774 105.753 l 0 18 612 756 re h EMC 0 -1.2 TD f q 600.467 684.507 l 363.104 106.521 m 600.467 493.384 l Q (with water in order to eliminate hazardous reactions since the materials\ generate their own oxygen. ( Do not induce vomiting. q /TT1 1 Tf (https://fscimage.fishersci.com/msds/95984.htm \(4 of 6\)7/23/2007 11:01:\ 40 AM)Tj ET /TT1 1 Tf /TT1 1 Tf /Article <>BDC 9.226 739.538 l Sens. 376.641 443.793 l 0 0 0 rg 0.949 0.945 0.935 rg ( )Tj 8.457 456.479 l ( CAS# 1333-82-0 is listed on the Canadian Ingredient Disclosure List\ . ( )Tj h )Tj ( )Tj ( )Tj Q The acid anhydride of chromic acid is chromium trioxide or chromium(VI) oxide; industrially, this compound is sometimes sold as "chromic acid". (hazard - See 29 CFR )Tj 9.226 133.047 l 123.434 66.926 l Chromium Trioxide, Crystal, Reagent, 25g Item # 39G248; Mfr. /TT0 1 Tf f (Health & Safety Reporting List)Tj SDS #: 243. (respiratory tract. 0 -1.1 TD Articles of chromium trioxide are included as well. 10.764 741.075 m EMC 0 -1.201 TD ( )Tj Do not breathe dust, mist, or vapor. f 9.226 53.471 l 602.774 677.857 l 603.543 119.976 l 1.506 -1.2 Td )Tj 600.467 684.507 l 9.226 701.717 l EMC 7.688 113.881 l 600.467 249.57 l 157.997 630.236 l )Tj 0.753 0.753 0.753 rg Q 0 -1.2 TD h h f 0 -1.2 TD (consequential or exemplary damages, howsoever arising, even if Fisher ha\ s been advised of the possibility of such damages. /Artifact <>BDC -6.946 -1.102 Td 604.312 51.934 l /Artifact <>BDC Its main use is in chrome-plating. 13.4548 0 0 13.4548 128.471 477.3716 Tm h /TT0 1 Tf q f )Tj 157.229 617.55 m 604.312 457.248 m h /Article <>BDC 454.771 541.819 l /TT1 1 Tf 8.457 106.521 m Hygroscopic: absorbs mo\ isture or water from )Tj 121.524 443.024 l W* n f 604.312 165.687 l /TT0 1 Tf 0 18 612 756 re 601.236 271.866 l (Chromium\(VI\) oxide)Tj q 15. 604.312 496.4 l 0 18 612 756 re 9.9358 0 0 9.9358 7.6884 43.7017 Tm EMC 0.457 0.449 0.431 rg Q f 0 18 612 756 re 0.949 0.945 0.935 rg 10.764 252.252 m 0 -1.1 TD 604.312 705.536 l 0 18 612 756 re f /Artifact <>BDC (US DOT)Tj ( exposure through inhalation. f f h 600.467 140.316 l 0 -1.1 TD endstream endobj 30 0 obj<>stream f /TT1 1 Tf 13.4548 0 0 13.4548 184.2679 146.6595 Tm High purity, submicron and nanopowder forms may be considered. ( Incompatible materials, dust generation, moisture, excess heat. (A100-100, A100-212, A100-500, A98-212, A98-500, NC9210244, S79969ACS, XX\ A100100LB )Tj 0.457 0.449 0.431 rg 0.753 0.753 0.753 rg /TT0 1 Tf 306 541.819 l f 11.533 410.348 l 0000001162 00000 n 121.524 443.024 m 9.226 542.588 l 601.236 157.65 l 9.226 92.298 l 602.774 407.621 l 157.229 631.005 l 0 -1.2 TD h 602.774 93.836 l f 9.226 494.862 l 377.41 429.569 l T* 602.774 727.858 l ( 1 Reagent Lane )Tj 7.688 541.05 l f Q /Artifact <>BDC ( Metals, reducing agents, combustible materials, halogens, sulfides, )Tj 0 -1.2 TD 156.46 542.588 l Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9623 Signal Word DANGER. ( )Tj 11.533 251.483 l 7.688 414.192 m 485.294 430.338 l 121.524 456.479 m 306 631.005 m /Artifact <>BDC Do NOT allow victim to rub eyes or keep ey\ es closed. f 123.434 78.843 l 9.226 491.077 593.548 26.141 re 601.236 140.022 l 602.774 227.648 l 0 -1.1 TD (CERCLA Hazardous Substances and corresponding RQs)Tj 0 -1.1 TD It can be prepared by adding concentrated sulphuric acid in potassium dichromate. 363.873 107.29 238.901 11.917 re Q W* n Q 0 18 612 756 re (Section 7 - Handling and Storage )Tj (pH:)Tj 306.769 618.319 147.234 11.917 re 0000001186 00000 n T* f h 602.774 677.857 l f /Artifact <>BDC /TT0 1 Tf Q /TT1 1 Tf W* n 120.755 442.255 l endstream endobj 32 0 obj<> endobj 33 0 obj<>stream The Professor shows us a tremendous reaction - but forgets to switch off the department smoke alarm. T* f 7.688 120.745 m EMC 5.3819 0 0 5.3819 27.4577 488.6831 Tm 11.533 139.253 l 0.457 0.449 0.431 rg C\ ontact with other material may cause fire. f Q Product form : Substance Strong oxidiz\ er. f Q 0 18 612 756 re f (This product has been classified in accordance with the hazard criteria \ of the Controlled Products Regulations and the )Tj T* 122.666 93.067 l 122.666 93.067 m 0 -1.201 TD f 9.226 703.998 l h Q (exposure to water insoluble hexavalent chromium compounds has been shown\ to be associated with lung cancer and )Tj (TDLO/TCLO-LOWEST PUBLISHED TOXIC DOSE/CONC. 603.543 443.024 l ( R 35 Causes severe burns. h Revision Date: 07/16/2001 Page 1 of 7 MATERIAL SAFETY DATA SHEET CHROMIC OXIDE 1. 0000000016 00000 n ( )Tj 600.467 677.859 l h Possible risk of harm to )Tj 603.543 79.612 l /Artifact <>BDC (safety shower. EMC 0 -1.1 TD 0 -1.1 TD )Tj 0.801 0.801 0.801 rg W* n q 0.753 0.753 0.753 rg (Exposure Limits)Tj f 7.688 729.395 m f /Artifact <>BDC ( R 42/43 May cause sensitization by inhalation and skin contact. f 11.533 684.507 l f 601.236 678.628 m 9.226 701.717 l Q f (Shipping Name:)Tj Remove contaminated clothing and wash b\ efore reuse. 11.533 706.034 l T* 362.335 53.471 l 0 0 0 rg 0.801 0.801 0.801 rg h ( 3.4 )Tj f ( None of the chemicals in this product are listed as Toxic Pollutant\ s under the CWA. 601.236 515.68 l 602.774 471.065 l 157.229 541.819 l 123.434 65.388 l 9.9358 0 0 9.9358 7.6884 656.8288 Tm (Massachusetts. 0 -1.201 TD h (US FEDERAL)Tj W* n h h 18.528 0 Td f /TT0 1 Tf Avoid contact with clothing and other combustible materi\ als. 604.312 729.395 m 7.688 705.536 m f 0.313 0.313 0.313 rg (Viscosity:)Tj /TT1 1 Tf May cause fire or explosion; strong … Not breathe dust, mist, or on clothing Monitoring methods BS EN 14042:2003 Title:! 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